Scott Mitchell has written a good series of articles on data structures in .NET.

This six-part series examines a variety of data structures, some of which are included in the .NET Framework Base Class Library and some of which are custom written. Please find it below..

Part 1. - An Extensive Examination of Data Structures
Part 2. - The Queue, Stack, and Hashtable
Part 3. - Binary Trees and BSTs
Part 4. - Building a Better Binary Search Tree
Part 5. - From Trees to Graphs
Part 6. - Efficiently Representing Sets

Details about the author can be found here...

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